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Standard hazard statements (H-phrases)

H Phrases Intro

What are H-phrases and why are they important?

Hazard Statements are standardized phrases that accurately describe the risks associated with chemical substances and mixtures. They are not general labels, but precise characteristics of the risk - for example, whether the product causes eye irritation, is flammable or poses a threat to the environment.

H-phrases are an integral part of the European CLP (Classification, Labelling and Packaging) system, i.e. the classification, labelling and packaging of chemical substances and mixtures, which is binding throughout the EU under Regulation (EC) No 1272/2008. This system is based on the international framework GHS (Globally Harmonised System), created by the United Nations (UN), which unifies the labelling of chemicals across countries and continents.

Main function of H phrases

H-phrases fulfill several important roles:

  • Health Protection – Inform workers, consumers and emergency services of the risks posed by the product – e.g. “H314 – Causes severe skin burns and eye damage”.

  • Standardization – Thanks to standardized numbering, H-phrases have a clear meaning that is maintained in all EU languages – making them easier to translate, check and understand across languages and countries.

  • Legally binding – Their inclusion on labels and safety data sheets is mandatory and legally enforceable. Incorrect use (e.g. paraphrasing or poor translation) may have legal consequences.

How are H-phrases divided?

Category
Hazard type
Example
H2xx
Physical hazards
Highly flammable liquid and vapour.
H3xx
Human health
Harmful if swallowed.
H4xx
Environment
Very toxic to aquatic life.

Use of H-phrases in practice

In the safety data sheet (SDS)

H-phrases play a key role in informing users about specific risks. They appear mainly in section 2.2 of the safety data sheet, where they appear together with:

  • P-phrases (instructions for safe handling),
  • signal word (“Danger” or “Warning”). Their text must correspond to the official text according to Annex III of the CLP Regulation.

It is not allowed to:

  • make your own translations,
  • modify the text,
  • paraphrase.

For example, the H319 sentence in the Czech translation always reads: “Causes serious eye irritation.”

It cannot be rewritten as, for example, “May irritate eyes.” – such text does not meet legal requirements and may lead to invalidation of the label or fines.

On the label

The label is often the only document available to the consumer. It must therefore contain all the information that will enable safe handling – and at the same time meet the legal requirements under the CLP Regulation. The H-phrases on the label must be:

  • legible and visible (correct font size, contrast),
  • stated in accordance with the classification of the entire mixture or substance
  • stated in full, without abbreviations

The order of the individual H and P-phrases on the label is not fixed – the supplier can choose it at his own discretion. However, it is important that:

  • the phrases are grouped by language – Czech must not be mixed with other languages within one section,
  • the phrases are exactly as worded according to CLP, without abbreviations or modifications – multilingual labels are clearly divided and all language versions are complete.

The label must also contain:

  • hazard warning symbols (e.g. flame, skull, exclamation mark),
  • signal word (“Danger” or “Warning”),
  • P-phrases – instructions for safe handling, e.g. “Wear safety glasses”.

New EUH phrases among standard phrases

As part of the revision of the CLP Regulation, new phrases designated as EUH have been added, which expand the existing labelling system to include additional specific risks not yet addressed by the GHS. Unlike the previous informative supplements, these new EUH phrases have the status of standard hazard statements.

EUH – Overview of the new standard EUH phrases:

Category
Hazard type
EUH380
May cause endocrine disruption in humans.
EUH381
Suspected of causing endocrine disruption in humans.
EUH430
May cause endocrine disruption in the environment.
EUH431
Suspected of causing endocrine disruption in the environment.
EUH440
Accumulates in the environment and living organisms including in humans.
EUH441
Strongly accumulates in the environment and living organisms including in humans.
EUH450
Can cause long-lasting and diffuse contamination of water resources.
EUH451
Can cause very long-lasting and diffuse contamination of water resources.

Like H-statements, these new EUH statements must appear on labels and safety data sheets if the product meets the criteria for classification. Their introduction represents a further step by the EU beyond the GHS and reflects current scientific knowledge – in particular in the areas of endocrine disruptors and environmental protection.

H Phrases List

List of H phrases

H2xx – Physical hazards

Codes
Version
H200
Unstable explosives.
H201
Explosive; mass explosion hazard.
H202
Explosive, severe projection hazard.
H203
Explosive; fire, blast or projection hazard.
H204
Fire or projection hazard.
H205
May mass explode in fire.
H206
Fire, blast or projection hazard; increased risk of explosion if desensitising agent is reduced.
H207
Fire or projection hazard; increased risk of explosion if desensitising agent is reduced.
H208
Fire hazard; increased risk of explosion if desensitising agent is reduced.
H220
Extremely flammable gas.
H221
Flammable gas.
H222
Extremely flammable aerosol.
H223
Flammable aerosol.
H224
Extremely flammable liquid and vapour.
H225
Highly flammable liquid and vapour.
H226
Flammable liquid and vapour.
H228
Flammable solid.
H229
Pressurised container: May burst if heated.
H230
May react explosively even in the absence of air.
H231
May react explosively even in the absence of air at elevated pressure and/or temperature.
H232
May ignite spontaneously if exposed to air.
H240
Heating may cause an explosion.
H241
Heating may cause a fire or explosion.
H242
Heating may cause a fire.
H250
Catches fire spontaneously if exposed to air.
H251
Self-heating: may catch fire.
H252
Self-heating in large quantities; may catch fire.
H260
In contact with water releases flammable gases which may ignite spontaneously.
H261
In contact with water releases flammable gases.
H270
May cause or intensify fire; oxidiser.
H271
May cause fire or explosion; strong oxidiser.
H272
May intensify fire; oxidiser.
H280
Contains gas under pressure; may explode if heated.
H281
Contains refrigerated gas; may cause cryogenic burns or injury.
H290
May be corrosive to metals.

H3xx – Human health

Codes
Version
H300
Fatal if swallowed.
H301
Toxic if swallowed.
H302
Harmful if swallowed.
H310
Fatal in contact with skin.
H311
Toxic in contact with skin.
H312
Harmful in contact with skin.
H330
Fatal if inhaled.
H331
Toxic if inhaled.
H332
Harmful if inhaled.
H304
May be fatal if swallowed and enters airways.
H314new
Causes severe skin burns and eye damage.
H315
Causes skin irritation.
H317
May cause an allergic skin reaction.
H318new
Causes serious eye damage.
H319
Causes serious eye irritation.
H334
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335
May cause respiratory irritation.
H336
May cause drowsiness or dizziness.
H340
May cause genetic defects.
H341
Suspected of causing genetic defects.
H350
May cause cancer.
H350i
May cause cancer by inhalation.
H351
Suspected of causing cancer.
H360
May damage fertility or the unborn child.
H360D
May damage the unborn child.
H360Df
May damage the unborn child. Suspected of damaging fertility.
H360F
May damage fertility.
H360FD
May damage fertility. May damage the unborn child.
H360Fd_
May damage fertility. Suspected of damaging the unborn child.
H361
Suspected of damaging fertility or the unborn child.
H361d
Suspected of damaging the unborn child.
H361f
Suspected of damaging fertility.
H361fd
Suspected of damaging fertility. Suspected of damaging the unborn child.
H362
May cause harm to breast-fed children.
H370
Causes damage to organs.
H371
May cause damage to organs.
H372
Causes damage to organs through prolonged or repeated exposure.
H373
May cause damage to organs through prolonged or repeated exposure.

H4xx – Environment

Codes
Version
H400
Very toxic to aquatic life.
H410
Very toxic to aquatic life with long lasting effects.
H411
Toxic to aquatic life with long lasting effects.
H412
Harmful to aquatic life with long lasting effects.
H413
May cause long lasting harmful effects to aquatic life.
H420
Harms public health and the environment by destroying ozone in the upper atmosphere.
H Phrases Outro

Resources

Regulation (EC) No 1272/2008 on classification, labelling and packaging of substance and mixtures - Consolidated version
This text is for informational purposes only and does not replace applicable legislation.

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